See List of Fifth Division Units
First Commander: Brigadier General Alexander William Doniphan
Second Commander: Brigadier General Jesse Morin
Third Commander: Brigadier General Alexander Early Steen
Fourth Commander: Colonel James P. Saunders
Fifth Commander: Brigadier General Alexander Early Steen
Sixth Commander: Colonel Alonzo W. Slayback
| Division Adjutant-General: | Colonel D. W. Floweree |
| Colonel Joseph M. Fox | |
| Assistant Division Adjutant-General: | Major George D. Shackleford |
| Division Comissary of Subsistence: | Lt. Colonel Boaz Roberts |
| Division Inspector-General: | Lt. Colonel Thomas W. Shields |
| Division Judge Advocate-General: | Lt. Colonel Alexander Harris |
| Division Paymaster-General: | Lt. Colonel James M. Loughborough |
| Lt. Colonel Thomas Thurman | |
| Division Quartermaster-General: | Lt. Colonel S. R. Shrader |
| Division Surgeon-General: | Lt. Colonel Charles N. Palmer, M.D. |
| Assistant Division Surgeon: | Major C. T. Hart, M.D. |
| Acting Ordnance Officer: | First Lieutenant Gillapie |
| Aides-de-Camp | Lt. Colonel Wright Schaumburg |
| Lt. Colonel James W. Gillespie | |
| Volunteer Aide-de-Camps: | Major George Washington Van Lear |
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Division | Third Division | Fourth
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Fifth Division | Sixth Division | Seventh Division | Eighth Division
Ninth Division